4-Amino-2-hydroxybenzohydrazide
نویسندگان
چکیده
The asymmetric unit of the title compound, C(7)H(9)N(3)O(2), comprises two crystallographically independent mol-ecules (A and B). In each mol-ecule there is an intra-molecular O-H⋯O hydrogen bond making an S(6) ring motif. In the crystal, a pair of N-H⋯N hydrogen bonds link the two mol-ecules (A and B) into a dimer with an R(2) (2)(6) ring motif. The B mol-ecules are linked via pairs of N-H⋯O hydrogen bonds, forming inversion dimers with an R(2) (2)(10) ring motif. The mol-ecules are further linked via other N-H⋯O hydrogen bonds, forming undulating two-dimensional networks lying parallel to the bc plane. These networks are finally linked via N-H⋯O hydrogen bonds, forming a three-dimensional structure.
منابع مشابه
N′-(2,4-Dichlorobenzylidene)-4-hydroxybenzohydrazide
The title hydrazone compound, C(14)H(10)Cl(2)N(2)O(2), was synthesized by the reaction of 2,4-dichloro-benzaldehyde and 4-hy-droxy-benzohydrazide. The mol-ecule adopts an E geometry with respect to the azomethine group and the dihedral angle between the aromatic rings is 7.0 (2)°. In the crystal, mol-ecules are linked through inter-molecular N-H⋯Cl and O-H⋯O hydrogen bonds, forming a three-dime...
متن کاملN′-[(Z)-(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)methylidene]-2-hydroxybenzohydrazide
In the title compound, C(19)H(18)N(4)O(3), the pyrazole ring is oriented at dihedral angles of 41.12 (7) and 12.25 (10)°, respectively, with respect to the planes of the phenyl and benzene rings. Intra-molecular N-H⋯O and O-H⋯O hydrogen bonds generate seven- and six-membered S(7) and S(6) ring motifs, respectively.
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The organic molecule of the title hydrate, C(15)H(13)BrN(2)O(4)·H(2)O, is roughly planar, with a mean deviation of 0.0939 (2) Å. The dihedral angle between the two aromatic rings is 8.2 (3)°. Intra-molecular O-H⋯N and O-H⋯O hydrogen bonds are observed. In the crystal, N-H⋯O(water) and O(water)-H⋯O hydrogen bonds lead to a three-dimensional network.
متن کاملN′-(2,6-Dichlorobenzylidene)-2-hydroxybenzohydrazide
In the title compound, C(14)H(10)Cl(2)N(2)O(2), the dihedral angle between the two aromatic rings is 17.39 (4)°. An intra-molecular O-H⋯O hydrogen bond forms a six-membered R(6)(1) (1 )ring motif. In the crystal structure, inter-molecular N-H⋯O and O-H⋯O hydrogen-bonding inter-actions occur.
متن کامل(E)-N′-[4-(Dimethylamino)benzylidene]-4-hydroxybenzohydrazide hemihydrate
In the title compound, C(16)H(17)N(3)O(2)·0.5H(2)O, the two hydrazide mol-ecules are approximately planar: the dihedral angles between the two substituted benzene rings are 7.7 (2) and 4.2 (2)°. Both hydrazone mol-ecules exist in a trans geometry with respect to their methyl-idene units. In the crystal, the water mol-ecule lies between the two organic mol-ecules and makes bifurcated O-H⋯(N,O) h...
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012